No. This product is not nightshades free as it lists 1 ingredient that contains nightshades.

Is M&S Food Made Without Wheat Gluten Free 4 Blueberry Muffins Nightshade Free?

No. This product is not nightshades free as it lists 1 ingredient that contains nightshades.
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Ingredients

Sugar, pasteurised egg, blueberries (17%), nut, potato starch, rapeseed oil, humectant: glycerol, rice flour, cornflour, lemon juice, dried skimmed milk, dried egg white, flavourings, raising agent: E501, E450, sodium bicarbonate, invert sugar syrup, stabiliser: xanthan gum, emulsifier: E481, E475, E471. Contains Egg, Milk, Egg, Not suitable for nut and peanut allergy sufferers.

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Nightshade Free? M&S Food Made Without Wheat Gluten Free 4 Blueberry Muffins | Spoonful